More Insight Into Cobalt as Catalyst for Water Splitting

Researchers from UC Davis and the Massachusetts Institute of Technology have uncovered more detail about the functioning of cobalt as a water-splitting catalyst. In 2008, MIT chemists, led by Professor Dan Nocera, reported that a simple cobalt catalyst could split water at neutral pH to produce oxygen, protons and electrons. The catalyst actually seems to assemble itself over several hours as an electric current is applied, and then begins to bubble oxygen. (Earlier post.)

This got a lot of attention from the chemistry community, but no one knew how it worked.

—R. David Britt, professor of chemistry at UC Davis

Britt’s lab is working with Nocera's group to use a technique called electron paramagnetic resonance to study the chemical state of cobalt atoms in the catalyst. They found that as more water is split, the proportion of cobalt (IV) increases and the proportion of cobalt (II) decreases. The work opens the door to further studies on these catalysts, the authors write.

Ultimately, catalysts based on relatively abundant elements like cobalt, as opposed to platinum or gold, could make it economical to convert electricity from solar panels or other renewable sources into hydrogen fuel for storage or use. The protons and electrons produced from splitting water would be used in the next step of the process to make hydrogen.

Electron paramagnetic resonance is a technique similar to the nuclear magnetic resonance used in medical imaging. Britt’s lab uses it to study catalysts that split water, including both artificial catalysts and those used by plants in photosynthesis.

A paper describing the work was published online 30 April in the Journal of the American Chemical Society.

Resources

• J. Gregory McAlpin, Yogesh Surendranath, Mircea Dinc, Troy A. Stich, Sebastian A. Stoian, William H. Casey, Daniel G. Nocera and R. David Britt (2010) EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH. J. Am. Chem. Soc., Article ASAP
  doi: 10.1021/ja1013344